塑料通用要求; (PP, PE, POM, PS, AS,PMMA, EVA,PET, PPS,PU材料只做通用要求) |
Order of 2/01/2003 |
A.總遷移--10%乙醇 Overall migration in 10% ethanol |
10mg/dm2 (嬰幼兒產品60mg/kg) |
EN1186-1; EN1186-3 |
1.依據(jù)客戶要求A可以改為水,D2可以改為95%乙醇或異辛烷; 2.A,C,D1三選一,默認做A; 3.接觸所有食物類型做A+B+D2 |
<3mg/dm2 |
B.總遷移--3 % 醋酸 Overall migration in 3% acetic acid |
EN1186-1; EN1186-3 |
<3mg/dm2 | ||||
C.總遷移--20%乙醇 Overall migration in 20% ethanol |
EN1186-1; EN1186-3 |
<3mg/dm2 | ||||
D1.總遷移--50%乙醇 Overall migration in 50% ethanol |
EN1186-1; EN1186-3 |
<3mg/dm2 | ||||
D2.總遷移--植物油 Overall migration in vegetable oil |
EN1186-1; EN1186-2 |
<3mg/dm2 | ||||
重金屬遷移 Specific migration of metals | 限值見備注7 | BS EN13130 -1:2004 | 見備注1 | ND,MDL | ||
初級芳香胺(PAA)遷移 Specific migration of primary aromatic amines(選做) | 0.01 mg/kg | BS EN13130 -1:2004 | 見備注1 | ND, MDL=0.01 | ||
默認項目:總遷移(10%乙醇,3%醋酸,植物油)+重金屬遷移 | ||||||
PC聚碳酸酯 | Order of 2/01/2003 | 塑料通用要求 | ||||
特殊遷移-雙酚A遷移 Specific migration of BPA |
0.6mg/kg | BS EN13130 -13:2004 | 見備注1 | ND, MDL=0.1 | ||
ABS丙烯腈- 苯乙烯- 丁二烯共聚物 | Order of 2/01/2003 | 塑料通用要求 | ||||
丁二烯遷移量 Specific migration of butadiene |
不得檢出 <0.01mg/kg |
BS EN13130 -15:2004 | 見備注1 | ND,MDL= 0.1mg/kg | ||
丙烯腈遷移量 Specific migration of acrylonitrile |
不得檢出 <0.01mg/kg |
BS EN13130 -3:2004 | 見備注1 | ND,MDL= 0.1mg/kg | ||
聚酰胺(尼龍PA) | Order of 2/01/2003 | 塑料通用要求 | ||||
(EU) No.284/2011 |
初級芳香胺(PAA) Specific migration of primary aromatic amines (必做) |
0.01 mg/kg | BS EN13130 -1:2004 | 見備注1 | ND, MDL=0.01 | |
(EU) No.284/2011 |
甲醛遷移量 Specific migration of formaldehyde |
15mg/kg | BS EN13130 -23:2004 |
見備注1; 塑料廚房用具建議做 |
ND, MDL=1 | |
特殊遷移-己內酰胺遷移(選做) Specific migration of Caprolactam |
15 mg/kg | BS EN13130 -16:2004 | 見備注1 | ND, MDL=5 | ||
三聚氰胺塑料 |
(EU) No.10/2011 |
塑料通用要求 | ||||
(EU) No.284/2011 |
初級芳香胺(PAA) (選做) |
0.01 mg/kg | BS EN13130 -1:2004 | 見備注1 | ND, MDL=0.01 | |
(EU) No.1282/2011 |
三聚氰胺單體遷移量 Special Migration of Melamine monomer |
2.5mg/kg | BS EN13130 -1:2004 | 見備注1 | ND, MDL=1 | |
甲醛遷移量 | 15mg/kg | BS EN13130 -23:2004 |
見備注1; 塑料廚房用具建議做 |
ND, MDL=1 | ||
聚氯乙烯(PVC) |
78/142/EEC Order of 2/01/2003 |
塑料通用要求 | ||||
氯乙烯單體含量content of vinyl chloride monomer(VCM) | 1 mg/kg |
80/766/EEC 參考書P86 |
ND, MDL=0.5 | |||
氯乙烯單體遷移量 Specific migration of vinyl chloride monomer |
不得檢出 <0.01mg/kg |
BS EN13130 -1:2004 |
81/432/EEC 參考書P91 |
ND, MDL=0.01 | ||
涂層 | AP(2004)1 | 同塑料通用要求 | ||||
硅膠 | Order of 09/11/1994 |
A.總遷移--10%乙醇 Overall migration in 10% ethanol |
10mg/dm2 (60mg/kg) 依據(jù)產品形狀 |
EN1186-1; EN1186-3 |
1.依據(jù)客戶要求A可以改為水,D2可以改為95%乙醇或異辛烷; 2.A,C,D1三選一,默認做A; 3.接觸所有食物類型做A+B+D2 |
<3mg/dm2 |
B.總遷移--3 % 醋酸 Overall migration in 3% acetic acid |
EN1186-1; EN1186-3 |
<3mg/dm2 | ||||
C.總遷移--20%乙醇 Overall migration in 20% ethanol |
EN1186-1; EN1186-3 |
<3mg/dm2 | ||||
D1.總遷移--50%乙醇 Overall migration in 50% ethanol |
EN1186-1; EN1186-3 |
<3mg/dm2 | ||||
D2.總遷移--植物油 Overall migration in vegetable oil |
EN1186-1; EN1186-2 |
<3mg/dm2 | ||||
揮發(fā)性有機物(VOM) Volatile organic matter |
0.005 | order of 25/11/1992, annex III, section2 | 200°C,4H | <0.1% | ||
過氧化值Peroxides | Absent | according to the French pharmacopoeia, Xth edition. | Absent | |||
有機錫遷移量Migration of organotin(As tin)(選做) | 0.1mg/kg | 見備注1 | ||||
橡膠 | Order of 09/11/1994 |
A.總遷移--10%乙醇 Overall migration in 10% ethanol |
10mg/dm2 (60mg/kg) 依據(jù)產品形狀 |
EN1186-1; EN1186-3 |
1.依據(jù)客戶要求A可以改為水,D2可以改為95%乙醇或異辛烷; 2.A,C,D1三選一,默認做A; 3.接觸所有食物類型做A+B+D2 |
<3mg/dm2 |
B.總遷移--3 % 醋酸 Overall migration in 3% acetic acid |
EN1186-1; EN1186-3 |
<3mg/dm2 | ||||
C.總遷移--20%乙醇 Overall migration in 20% ethanol |
EN1186-1; EN1186-3 |
<3mg/dm2 | ||||
D1.總遷移--50%乙醇 Overall migration in 50% ethanol |
EN1186-1; EN1186-3 |
<3mg/dm2 | ||||
D2.總遷移--植物油 Overall migration in vegetable oil |
EN1186-1; EN1186-2 |
<3mg/dm2 | ||||
揮發(fā)性有機物(VOM) Volatile organic matter |
0.005 | order of 25/11/1992, annex III, section2 | 105°C,4H | <0.1% | ||
過氧化值Peroxides value (選做) |
Absent | according to the French pharmacopoeia, Xth edition. | Absent | |||
芳香胺遷移量 Migration of aromatic amines(選做) | 1mg/kg | BS EN13130 -1:2004 | 見備注1 | ND,MDL=0.1 | ||
甲醛遷移量Migration of formaldehyde(選做) | 3mg/kg | BS EN13130 -23:2004 | 見備注1 | ND,MDL=1 | ||
N-亞硝銨遷移Migration of N-nitrosamines |
奶嘴10ug/kg產品 其它1ug/dm2 |
EN 12868:1999 食品模擬物 |
ND,MDL | |||
N-亞硝基化合物遷移Migration of Nnitrosatable substances |
奶嘴100ug/kg產品 其它10ug/dm2 |
ND,MDL | ||||
金屬通用要求 | CM/Res(2013)9與食品接觸的金屬和合金指南 | 23項重金屬溶出-人工自來水Eau du robinet artificielle DIN 10531 | 除酸性以外物質(包括干性) | ND,MDL | ||
23項重金屬溶出-0.5%檸檬酸 (PH<4.5)Extractable Heavy metals in 0.5% citric acid |
接觸酸性物質(PH≤4.5) | ND,MDL | ||||
7項重金屬溶出 | 7項重金屬溶出(老標準)Ni,Cd,Cr,Pb,Co,Cu,Sb | 見備注1; | ND,MDL | |||
不銹鋼-1 | DM-4B-COM-001-V01 | 金屬通用要求 | ||||
成分分析(碳,硅,錳,磷,硫,鎳) | 不同類型要求不一致(DM/4B/COM/001附件4) | EPA3050B | ND,MDL=2 | |||
鉻Cr含量 | Cr≥13% | EPA3050B | ||||
鉭tantalum(Ta), 鈮niobium(Nb), 鋯zirconium(Zr) |
分別<1% | EPA3050B | ||||
鉬molybdenum(Mo), 鈦titanium(Ti), 鋁aluminum(Al), 銅copper(Cu) |
分別<4% | EPA3050B | ||||
鋼鐵材料(包裝)-3a | DM-4B-COM-001-V01 | 金屬成分(22個元素) | 見備注3 | EPA3050B | ||
不良元素鉛鎘砷鈷(已包括在上面22個元素中) |
Pb < 0,010 % Cd < 0,010 % As < 0,030 % Co < 0,050% |
EPA3050B | ||||
鋼鐵材料-帶金屬鍍層(包裝)-3b | DM-4B-COM-001-V01 | 基材金屬成分滿足對應的鋼鐵材料(包裝)的要求 | EPA3050B | |||
錫鍍層需要滿足BSEN610關于99.85錫的要求,需要測試(Al, As,Bi,Cd,Cu,Fe,Pb,Sb,Zn) | 見備注4 | EPA3050B | ||||
鍍層不良元素鉛,鎘,砷 |
Pb < 0,010 % Cd < 0,010 % As < 0,030 % Co < 0,050% |
EPA3050B | ||||
鋼鐵材料-帶有機涂層(包裝)-3c | DM-4B-COM-001-V01 |
涂層見塑料要求 (干性食物不需要做遷移) |
PH值<4.5的酸性條件用10%的乙醇模擬物 | |||
基材需要滿足對應金屬的要求(選做) | ||||||
不沾有機涂層六價鉻遷移 | 5ug/dm2 | |||||
鋼鐵材料(非包裝)-4 | DM-4B-COM-001-V01 | 金屬成分(21個元素) | 見備注5 | 如餐具,廚具 | ||
不良元素鉛,鎘,砷(已包括在上面21個元素中) |
Pb<0.05%; Cd<0.01%; AS<0.03% |
|||||
鋼鐵和不銹鋼-帶金屬鍍層(非包裝)-5a | DM-4B-COM-001-V01 | 基材金屬成分滿足對應的不銹鋼和鋼鐵材料(非包裝)的要求 | ||||
鍍層不良元素鉛,鎘,砷、鈷 |
Pb < 0,010 % Cd < 0,010 % As < 0,030 % Co < 0,050% |
|||||
重金屬鎳,鉻,鋅遷移(當鍍層分別是鎳,鉻,鋅時) |
Ni:0.5mg/kg; Cr:5mg/kg; Zn:10mg/kg模擬物 |
干性食物不需要做遷移 | 水性:去離子水 | |||
PH≤4.5:0.5%檸檬酸; | ||||||
酒類:10%或更高濃度的乙醇 | ||||||
脂類:油2h | ||||||
鋼鐵和不銹鋼-帶有機涂層(非包裝)-5b | Order of 15/11/1945 |
涂層見塑料要求 (干性食物不需要做遷移) |
PH值<4.5的酸性條件用10%的乙醇模擬物 | |||
不沾有機涂層六價鉻遷移 | 5ug/dm2 | |||||
基材需要滿足對應金屬的要求(選做) | ||||||
鋁及鋁合金-2 | DM-4B-COM-001-V01 | 鋁材金屬成分元素含量(Fe, Si, Ti, Cr, Zn, Cu, Mn, Mg, Ni, Sn, Pb, Ti, Be共13個元素) | 見備注6 | |||
鋁合金金屬成分元素含量(Si, Sb, Sn, Mg, Cr, Mn, Ti, Ni, Zr, Fe, Zn, Cu, Sr, As, Ta, Be, Ti, Pb共18個元素) | 見備注6 | |||||
涂層見塑料要求 (干性食物不需要做遷移)需要 |
PH值<4.5的酸性條件用10%的乙醇模擬物(乙醇10 % *包裝食品(飲料罐,輕罐頭=) 乙酸3 % *為其他應用程序,如餐具和家居用品(鍋,平底鍋,菜……)和設備 所有的食品(包括食品除酸干品)) |
|||||
鑄鐵(如鐵鍋) | 鉛 | ≤0.05% | ||||
帶金屬鍍層的鑄鐵-5a | DM-4B-COM-001-V01 | 基材鉛 | ≤0.05% | |||
鍍層不良元素鉛,鎘,砷 |
Pb≤0.050%; Cd≤0.010%; AS≤0.030% |
|||||
重金屬鎳,鉻,遷移(當鍍層分別是鎳,鉻時) |
Ni:0.5mg/kg; Cr:5mg/kg食物 |
水性:去離子水 | ||||
PH≤4.5:0.5%檸檬酸; | ||||||
酒類:10%或更高濃度的乙醇 | ||||||
脂類:油2h | ||||||
帶有機涂層的鑄鐵-5b | 涂層見塑料要求 | |||||
基材需要滿足對應金屬的要求(選做) | ||||||
不沾有機涂層六價鉻遷移 | 5ug/dm2 | |||||
錫及錫合金-7 | DM-4B-COM-001-V01 | 錫含量 | ≥97% | |||
不良元素鉛,鎘,砷 |
Pb≤0.050%; Cd≤0.010%; AS≤0.030% |
|||||
銻antimony(Sb); 銅copper(Cu) |
Sb≤ 2.5%; Cu≤ 1.5% |
|||||
鋅及鋅合金-8 | DM-4B-COM-001-V01 | 鋅含量 | ≥99.85% | |||
不良元素鉛,鎘,砷 |
Pb≤0.05%; Cd≤0.01%; AS≤0.03% |
|||||
鋅遷移Specific migration of Zn | 10mg/kg食物 | |||||
其它金屬材料-9 | 不良元素鉛,鎘,砷 |
Pb≤0.050%; Cd≤0.010%; AS≤0.030% |
||||
重金屬遷移(Ni,Cr,Zn,Pb,Cd) Specific migration of metals |
Ni:0.5; Cr:5; Zn:10; Pb:4.0; Cd:0.3mg/kg |
|||||
玻璃、水晶、陶瓷、搪瓷制品 | DM-4B-COM-002-V01 | 鉛 | 見備注2 | 4%醋酸22℃24h | ND,MDL | |
鎘 | 見備注2 | ND,MDL | ||||
六價鉻(不適用于陶瓷) | Flatware:0.005mg/dm2 | ND,MDL | ||||
Hollowware(>3L):0.03mg/l | ||||||
Hollowware(<3L):0.03mg/l | ||||||
Lip and rim:0.015mg/unit | ||||||
鋁(不適用與口腔直接接觸) | 1mg/kg | 4%醋酸22℃24h,重復使用的制品需遷移3次,以第3次為最終結果 | ND,MDL | |||
鈷(不適用與口腔直接接觸) | 0.02mg/kg | ND,MDL | ||||
砷(不適用與口腔直接接觸) | 不得檢出(檢出限為0.002mg/kg) | ND,MDL | ||||
木制品 | AP(2004)2 | 五氯苯酚 | 殘留量0.15mg/kg | EN15320 | ||
甲醛遷移量 Specific migration of formaldehyde | Limit:15mg/kg食品 | EN13130-1 | 見備注1 | ND, MDL=1 | ||
紙和紙板 |
CSHPF 13/10/98 CSHPF 7/11/95 |
感觀測試 Organoleptic inertia | Absence | EN 1230-2 | absent | |
五氯苯酚含量Pentachlorophenol (PCP) content | ≤ 0.1 mg/kg of paper | EN/ISO 15320 | ND,MDL=0.05 | |||
甲醛遷移migration of Formaldehyde | ≤ 1 mg/dm² | 采用EN645冷水萃取或EN647熱水萃取,BSEN1541-2001測定 | ND,MDL=0.5 | |||
可萃取重金屬extractable heavy metals (Pb, Cd,Hg, CrVI) |
Pb≤3 mg/kg paper Cd≤0.5 mg/kg Hg≤0.3 mg/kg CrVI≤0.25 mg/kg |
采用EN645冷水萃取或EN647熱水萃取,ENV 12497 (Hg) ENV12498 (Pb, Cr, Cd) |
ND,MDL | |||
色牢度Fastness to bleeding colorants | 5級 | EN 646 or EN648 | 具體級數(shù) | |||
熱萃取物Hot extraction | 10 mg/dm² or 10 mg/g of paper | EN 920 | <3mg/dm2 | |||
多氯聯(lián)苯含量Polychlorobiphenyl (PCB) content | ≤ 2 mg/kg of paper | EN/ISO 15318 | ND,MDL=1 | |||
乙二醛遷移Glyoxal extractable (選做) | ≤ 1.5 mg/dm² | ND,MDL=0.5 | ||||
抗菌成分遷移Transfer of antimicrobial constituents (選做) |
No Transfer of antimicrobial agents | BS EN 1104-2005 | 沒有抗菌成分遷移 | |||
1、干性食物需要測試:感官,PCP,PCB,甲醛遷移,乙二醛遷移,抗菌成分遷移; 2、液體或脂類食物:除了熱萃取物之外,其它項目都要做; 3、熱過濾產品:感官,PCP,PCB,可萃取重金屬,熱萃取物,抗菌成分遷移; 4、烹飪產品:感官,PCP,PCB,可萃取重金屬,抗菌成分遷移。 |